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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)

Crystallographic observation of an olefin photodimerization reaction that takes place via thermal molecular tumbling within a self-assembled host.

In situ crystallography reveals that the solid state [2 + 2] photodimerization of acenaphthylene in a coordination cage takes place smoothly without preorganizaiton of reaction centers at a preferred geometry, because the substrate tumbles thermally in the large hollow of the cage.[1]


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