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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Water-Triggered and Gold(I)-Catalyzed Cascade Addition/Cyclization of Terminal Alkynes with ortho-Alkynylaryl Aldehyde.

A highly efficient alkynylation-cyclization of terminal alkynes with ortho-alkynylaryl aldehydes leading to 1-alkynyl-1H-isochromenes was developed by using a gold-phosphine complex as catalyst in water. The reaction was dually promoted by an electron-donating phosphine ligand and water and was chelation-controlled.[1]

References

  1. Water-Triggered and Gold(I)-Catalyzed Cascade Addition/Cyclization of Terminal Alkynes with ortho-Alkynylaryl Aldehyde. Yao, X., Li, C.J. Org. Lett. (2006) [Pubmed]
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