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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)

Advances in lewis Acid controlled carbon-carbon bond-forming reactions enable a concise and convergent total synthesis of bullatacin.

Lewis acids control regioselectivity in the alkylation of epi-chlorohydrin and the stereochemistry of an alkyne addition to set the C24/ C23 anti relationship. These advances facilitate an efficient total synthesis of bullatacin in 13.3% overall yield from commercial starting materials.[1]


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