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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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New regiocontrolled synthesis of functionalized pyrroles from 2-azetidinone-tethered allenols.

A new one-pot approach to synthesize densely substituted racemic and enantiopure pyrroles from beta-lactams has been developed. The approach relies on the regiocontrolled cyclization of beta-allenamine intermediates derived from the ring opening of 2-azetidinone-tethered allenols. In this approach four points of diversity are introduced, one of which is the position of the allene moiety on the beta-lactam ring.[1]

References

  1. New regiocontrolled synthesis of functionalized pyrroles from 2-azetidinone-tethered allenols. Alcaide, B., Almendros, P., Carrascosa, R., Redondo, M.C. Chemistry (2008) [Pubmed]
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