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Selective oxidation of cyclohexanol to cyclohexanone in the ionic liquid 1-octyl-3-methylimidazolium chloride.

Ionic liquid (IL) 1-octyl-3-methylimidazolium chloride was found to effectively intensify cyclohexanol oxidation and resulted in 100% conversion of cyclohexanol with 100% selectivity to cyclohexanone using hydrogen peroxide as an oxidant and WO(3) as a catalyst. The effect of the IL as a solvent is discussed with the support of COSMO-RS theory.[1]

References

  1. Selective oxidation of cyclohexanol to cyclohexanone in the ionic liquid 1-octyl-3-methylimidazolium chloride. Chen, L., Zhou, T., Chen, L., Ye, Y., Qi, Z., Freund, H., Sundmacher, K. Chem. Commun. (Camb.) (2011) [Pubmed]
 
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