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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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A novel synthesis of carbocyclic C-nucleoside precursors by nonoxidative C-C bond fission.

New carbocyclic c-nucleoside precursors have been synthesized in stereocontrolled manner by nonoxidative C-C bond fission (i.e., Grob fragmentation or retrograde aldol reaction) starting from Diels-Alder adducts of cyclopentadiene with 3-acetoxyacrylates or dimethyl 2-acetoxymethylenemalonate.[1]

References

  1. A novel synthesis of carbocyclic C-nucleoside precursors by nonoxidative C-C bond fission. Katagiri, N., Haneda, T., Tomizawa, S., Kaneko, C. Nucleic Acids Symp. Ser. (1986) [Pubmed]
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