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Brosius, A.D. et al.

Brosius, Ziller, Zhang,

Relative and absolute configuration of aloperine.

The relative and absolute configuration of the title compound, (6R,7R,9R,11S)-16,17-didehydro-9-de-2-piperidinylormosanine, C15H24N2, has been elucidated. Two X-ray structures, one of the free base of the alkaloid and the second of its dihydrochloride monohydrate salt, C15H26N2(2+).2Cl-.H2O, have been determined to unequivocally establish the stereochemistry of aloperine, the parent member of a rare family of lupinine alkaloids.[1]

References

Relative and absolute configuration of aloperine. Brosius, A.D., Ziller, J.W., Zhang, Q. Acta crystallographica. Section C, Crystal structure communications. (1997) [Pubmed]

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