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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Chemical Compound Review: 

gallium(3+)     gallium(+3) cation

Synonyms: gallium-67(3+), AGN-PC-0052G4, Gallium cation, Ga(3+), AC1L2Y4H, ...
 
 
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High impact information on Gallium (III) ion

  • A highly sensitive and selective capillary zone electrophoresis with laser-induced fluorescence detection (CZE-LIF) for Al(3+) and Ga(3+) was developed using a calcein 4',5'-isomer as a pre-capillary complexing agent [1].
  • This paper focuses on the hydrolysis of Ni(2+) and Ga(3+) ions, together in solution, carried out by base addition [2].
  • The presence of trivalent metal ions Cr(3+), Ga(3+), Fe(3+) and Al(3+) was found to quench the resulting chemiluminescence dramatically [3].
 

Biological context of Gallium (III) ion

  • The samples will be defined by their hydrolysis ratio R = [OH(-)]/([Ni(2+)] + [Ga(3+)]) [2].
 

Analytical, diagnostic and therapeutic context of Gallium (III) ion

  • In contrast, the replacement by Ga(3+) yielded a much more disordered local environment of the probe atom in all investigated cell culture samples [4].
  • Spectrophotometric titrations in the UV region revealed that L is able to bind Ga(3+) also at high H(+) concentration [5].

References

  1. Selective ultratrace detection of Al(III) and Ga(III) complexed with a calcein isomer by capillary zone electrophoresis with laser-induced fluorescence detection Comparison of emissive polyaminocarboxylates as derivatizing ligands. Saito, S., Shimidzu, J., Yoshimoto, K., Maeda, M., Aoyama, M. Journal of chromatography. A (2007) [Pubmed]
  2. Synthesis of NiGa layered double hydroxides. A combined EXAFS, SAXS, and TEM study. 2. Hydrolysis of a Ni2+/Ga3+ solution. Defontaine, G., Michot, L.J., Bihannic, I., Ghanbaja, J., Briois, V. Langmuir : the ACS journal of surfaces and colloids. (2004) [Pubmed]
  3. Effects of some trivalent metal ions on the fluoride-induced chemiluminescence from a phenylphosphate-substituted dioxetane Lumigen PPD. Shamsipur, M., Chaichi, M.J. Luminescence : the journal of biological and chemical luminescence. (2002) [Pubmed]
  4. Bone tissue incorporates in vitro gallium with a local structure similar to gallium-doped brushite. Korbas, M., Rokita, E., Meyer-Klaucke, W., Ryczek, J. J. Biol. Inorg. Chem. (2004) [Pubmed]
  5. A macrocyclic ligand able to bind gallium(III) by preorganized pendant arms; coordination and kinetic studies. Ambrosi, G., Boggioni, A., Formica, M., Fusi, V., Giorgi, L., Lucarini, S., Micheloni, M., Secco, F., Venturini, M., Zappia, G. Dalton transactions (Cambridge, England : 2003) (2005) [Pubmed]
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