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Chemical Compound Review: 

Trichloroboron     trichloroborane

Synonyms: Boron chloride, ARONIS23907, HSDB 326, AG-C-78992, ANW-14766, ...
 
 
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High impact information on trichloroborane

  • A method for preparing glycerophosphoesters from ether phospholipids by dealkylation with boron trichloride (BCl3) is described [1].
  • [reaction: see text] The reaction of boron tribromide and boron trichloride with 2-alkylidenetetrahydrofurans, readily available on the basis of cyclizations of free and masked dianions with 1,2-dielectrophiles, allowed an efficient synthesis of a variety of carbonyl compounds with remote halide functionality [2].
  • The boron trichloride/2-chlorethanol gave poor or little esterification with these 2 acids under the various conditions investigated [3].

References

  1. Quantitative conversion of diether or tetraether phospholipids to glycerophosphoesters by dealkylation with boron trichloride: a tool for structural analysis of archaebacterial lipids. Nishihara, M., Koga, Y. J. Lipid Res. (1988) [Pubmed]
  2. Convenient synthesis of epsilon-halo-beta-ketoesters and gamma,gamma'-dibromoalkanones by regio- and chemoselective reaction of 2-alkylidenetetrahydrofurans with boron trihalides: a "ring-closure/ring-cleavage" strategy. Bellur, E., Langer, P. J. Org. Chem. (2005) [Pubmed]
  3. Analysis of pesticides by chemical derivatization. I. a new procedure for the formation of 2-chloroethyl esters of ten herbicidal acids. Chau, A.S., Terry, K. Journal - Association of Official Analytical Chemists. (1975) [Pubmed]
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