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Chemical Compound Review: 

germyl     $l^{3}-germane

Synonyms: GeH3, Germyl radical, CHEBI:30555, GeH3(.), (GeH3)(.)
 
 
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High impact information on Germyl radical

  • Intramolecular homolytic translocation chemistry: an ab initio study of 1,n-silyl, germyl, and stannyl group transfer and related ring-closure reactions [1].
  • X-ray diffraction data for 5 indicate that the germyl ligand is bonded to rhenium, but positional disorder of the phenyl and Dipp groups prevented refinement of accurate metric parameters [2].

References

  1. Intramolecular homolytic translocation chemistry: an ab initio study of 1,n-silyl, germyl, and stannyl group transfer and related ring-closure reactions. Matsubara, H., Schiesser, C.H. J. Org. Chem. (2003) [Pubmed]
  2. Synthesis and reactivity of tris(imido)rhenium complexes containing rhenium-main group element bonds. silicon-carbon bond activations of PhSiH(3) by silyl complexes. Gavenonis, J., Tilley, T.D. Inorganic chemistry. (2004) [Pubmed]
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