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Chemical Compound Review

stannyl     $l^{3}-stannane

Synonyms: tin trihydride, CHEBI:30559, SnH3(.), (SnH3)(.), trihydridotin(.)
 
 
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Psychiatry related information on tin trihydride

  • The results show that the stannyl ester is effectively labelled with short reaction times giving reproducible yields from 85% to 95% [1].
 

High impact information on tin trihydride

  • The cyclizations are interpreted in terms of generation of an alkyl radical by abstraction of the nitro group with a stannyl radical [2].
  • Ruthenium-catalyzed hydrogenation of alkynylstannanes with migration of the stannyl group [3].
  • Successful realization of the sharp discrimination between PCR and CICR has led to the creation of [(125)I]GIF-0082 and [(125)I]GIF-0276, which were synthesized by substituting a stannyl group with (125)I in the corresponding phenylstannane precursors [4].
  • Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, and trimethylgermyl derivatives of 3,3-dimethylcyclopropene. VI: Application of observed trends to stannyl derivatives [5].
 

Analytical, diagnostic and therapeutic context of tin trihydride

References

  1. Chloramine-T in high-specific-activity radioiodination of antibodies using N-succinimidyl-3-(trimethylstannyl)benzoate as an intermediate. Lindegren, S., Skarnemark, G., Jacobsson, L., Karlsson, B. Nucl. Med. Biol. (1998) [Pubmed]
  2. Stereochemical memory effects in alkene radical cation/anion contact ion pairs: effect of substituents, and models for diastereoselectivity. Crich, D., Ranganathan, K. J. Am. Chem. Soc. (2005) [Pubmed]
  3. Ruthenium-catalyzed hydrogenation of alkynylstannanes with migration of the stannyl group. Shirakawa, E., Morita, R., Tsuchimoto, T., Kawakami, Y. J. Am. Chem. Soc. (2004) [Pubmed]
  4. [(125)I]-N-[(3-azido-5-iodo)benzyl]dantrolene and [(125)I]-N-[[3-iodo-5-(3-trifluoromethyl-3H-diazirin-3-yl)]benzyl]dantrolene: photoaffinity probes specific for the physiological Ca(2+) release from sarcoplasmic reticulum of skeletal muscle. Hosoya, T., Aoyama, H., Ikemoto, T., Hiramatsu, T., Kihara, Y., Endo, M., Suzuki, M. Bioorg. Med. Chem. Lett. (2002) [Pubmed]
  5. Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, and trimethylgermyl derivatives of 3,3-dimethylcyclopropene. VI: Application of observed trends to stannyl derivatives. Panchenko, Y.N., De Maré, G.R., Abramenkov, A.V., Baird, M.S., Tverezovsky, V.V., Nizovtsev, A.V., Bolesov, I.G. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. (2004) [Pubmed]
  6. Synthesis and radioiodination of a stannyl oligodeoxyribonucleotide. Dougan, H., Hobbs, J.B., Weitz, J.I., Lyster, D.M. Nucleic Acids Res. (1997) [Pubmed]
 
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