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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Chemical Compound Review: 

SiH2     $l^{2}-silane

Synonyms:
 
 
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High impact information on Silylene

  • The UV/vis spectrum of the silylene in anhydrous hexane at 25 degrees C, determined by laser flash photolysis methods, agrees well with that obtained in frozen hydrocarbon matrixes, and that of the dimerization product, tetraphenyldisilene, is tentatively assigned [1].
  • Silapropargyl/silaallenyl and silylene acetylide complexes of [Cp(CO)2W]+. Theoretical study of their interesting bonding nature and formation reaction [2].
  • Synthesis, light-harvesting and energy-transfer properties of regioregular silylene-spaced alternating [(donor-SiMe2-)(n=1-3)-(acceptor-SiMe2)] copolymers [3].
  • Time-resolved kinetic studies of the reaction of silylene, SiH2, generated by laser flash photolysis of both silacyclopent-3-ene and phenylsilane, have been carried out to obtain second-order rate constants for its reaction with CH3Cl [4].
  • Time-resolved kinetic studies of the reaction of silylene, SiH2, generated by laser flash photolysis of phenylsilane, have been carried out to obtain rate constants for its bimolecular reaction with NO [5].
 

Biological context of Silylene

References

  1. Diphenylsilylene. Moiseev, A.G., Leigh, W.J. J. Am. Chem. Soc. (2006) [Pubmed]
  2. Silapropargyl/silaallenyl and silylene acetylide complexes of [Cp(CO)2W]+. Theoretical study of their interesting bonding nature and formation reaction. Ray, M., Nakao, Y., Sato, H., Sakaba, H., Sakaki, S. J. Am. Chem. Soc. (2006) [Pubmed]
  3. Synthesis, light-harvesting and energy-transfer properties of regioregular silylene-spaced alternating [(donor-SiMe2-)(n=1-3)-(acceptor-SiMe2)] copolymers. Cheng, Y.J., Luh, T.Y. Chemistry (Weinheim an der Bergstrasse, Germany) (2004) [Pubmed]
  4. Time-resolved gas-phase kinetic and quantum chemical studies of reactions of silylene with chlorine-containing species. 2. CH3Cl. Becerra, R., Cannady, J.P., Walsh, R. The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory. (2006) [Pubmed]
  5. Time-resolved gas-phase kinetic and quantum chemical studies of the reaction of silylene with nitric oxide. Becerra, R., Bowes, S.J., Ogden, J.S., Cannady, J.P., Almond, M.J., Walsh, R. The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory. (2005) [Pubmed]
  6. Silylene-bridged dinuclear iron complexes [Cp(OC)2Fe]2SiX2 (X = H, F, Cl, Br, I). Synthesis, molecular structure, vibrational spectroscopy, and theoretical studies. Vögler, M., Pavel, I., Hofmann, M., Moigno, D., Nieger, M., Kiefer, W., Malisch, W. Inorganic chemistry. (2003) [Pubmed]
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