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Chemical Compound Review

CID6357     aluminum(+3) cation; carbanide

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High impact information on TRIMETHYLALUMINIUM

  • Molecular dynamics simulations at the MP2 level of theory were carried out for presumed elementary steps in MAO formation via hydrolysis of trimethylaluminum (TMA) [1].
  • Rapid cyclization using a microwave-assisted Paal-Knorr reaction provided a set of 24 pyrrole esters that were further functionalized through a trimethylaluminum-mediated aminolysis to obtain a larger library of 288 diverse pyrrole-3-amides [2].

Associations of TRIMETHYLALUMINIUM with other chemical compounds


  1. Methyaluminoxane (MAO) polymerization mechanism and kinetic model from ab initio molecular dynamics and electronic structure calculations. Negureanu, L., Hall, R.W., Butler, L.G., Simeral, L.A. J. Am. Chem. Soc. (2006) [Pubmed]
  2. Solution phase synthesis of a library of tetrasubstituted pyrrole amides. Bianchi, I., Forlani, R., Minetto, G., Peretto, I., Regalia, N., Taddei, M., Raveglia, L.F. Journal of combinatorial chemistry. (2006) [Pubmed]
  3. An efficient synthesis of 3-substituted 3H-pyrimidin-4-ones. Jeong, J.U., Chen, X., Rahman, A., Yamashita, D.S., Luengo, J.I. Org. Lett. (2004) [Pubmed]
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