Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)

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Chemical Compound Review:

CID6357 aluminum(+3) cation; carbanide

Synonyms:

Bianchi, I. et al., Negureanu, L. et al., Jeong, J.U. et al.

Jeong, Chen, Rahman, Yamashita, Luengo,

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High impact information on TRIMETHYLALUMINIUM

Molecular dynamics simulations at the MP2 level of theory were carried out for presumed elementary steps in MAO formation via hydrolysis of trimethylaluminum (TMA) [1].
Rapid cyclization using a microwave-assisted Paal-Knorr reaction provided a set of 24 pyrrole esters that were further functionalized through a trimethylaluminum-mediated aminolysis to obtain a larger library of 288 diverse pyrrole-3-amides [2].

Associations of TRIMETHYLALUMINIUM with other chemical compounds

The key step involves the cyclization of enamide esters, derived from readily available beta-keto esters, with trimethylaluminum and various primary amines [3].

References

Methyaluminoxane (MAO) polymerization mechanism and kinetic model from ab initio molecular dynamics and electronic structure calculations. Negureanu, L., Hall, R.W., Butler, L.G., Simeral, L.A. J. Am. Chem. Soc. (2006) [Pubmed]
Solution phase synthesis of a library of tetrasubstituted pyrrole amides. Bianchi, I., Forlani, R., Minetto, G., Peretto, I., Regalia, N., Taddei, M., Raveglia, L.F. Journal of combinatorial chemistry. (2006) [Pubmed]
An efficient synthesis of 3-substituted 3H-pyrimidin-4-ones. Jeong, J.U., Chen, X., Rahman, A., Yamashita, D.S., Luengo, J.I. Org. Lett. (2004) [Pubmed]

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