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Chemical Compound Review

Olean     1,7-dioxaspiro[5.5]undecane

Synonyms: Eco-Trap, D7151_ALDRICH, AG-K-94413, SureCN1720520, ACMC-20ap0w, ...
 
 
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Analytical, diagnostic and therapeutic context of EINECS 205-870-7

  • The enantiomers of racemic olive fly sex pheromone 1,7-dioxaspiro[5.5]undecane (1) have been isolated by crystallization with enantiospecific cyclodextrin hosts: (S)-(1) crystallizes with heptakis(2,3,6-tri-O-methyl)-beta-cyclodextrin (TMbetaCD) and (R)-(1) with hexakis(2,3,6-tri-O-methyl)-alpha-cyclodextrin (TMalphaCD) [1].
  • The results obtained strongly indicate that this technique, to our knowledge the first insect pheromone enzyme-linked immunosorbent assay so far reported, is a fast, sensitive, inexpensive, and highly convenient method for the analysis of a volatile and low molecular weight compound such as 1,7-dioxaspiro[5.5]undecane, 1 [2].

References

  1. Non-covalent interactions in the crystallization of the enantiomers of 1,7-dioxaspiro. Makedonopoulou, S., Yannakopoulou, K., Mentzafos, D., Lamzin, V., Popov, A., Mavridis, I.M. Acta Crystallogr., B (2001) [Pubmed]
  2. Synthesis of haptens and development of an immunoassay for the olive fruit fly pheromone. Neokosmidi, A., Ragoussis, V., Zikos, C., Paravatou-Petsotas, M., Livaniou, E., Ragoussis, N., Evangelatos, G. J. Agric. Food Chem. (2004) [Pubmed]
 
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