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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Conversion of cefamandole nafate to cefamandole sodium.

The rate of hydrolysis of the formyl moiety of cefamandole nafate was determined as a function of pH, temperature, and concentration of added sodium carbonate or tromethamine. The reaction rate was sensitive to hydroxide ion in the pH 5.5-8.0 range with half-life values of hours to minutes. Hydrolysis was rapid upon the addition of sodium carbonate or tromethamine. Chirality in the 7-D-mandelamido side chain was unaffected by hydrolysis.[1]

References

  1. Conversion of cefamandole nafate to cefamandole sodium. Indelicato, J.M., Wilham, W.L., Cerimele, B.J. Journal of pharmaceutical sciences. (1976) [Pubmed]
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