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Stereoselective synthesis of 2-hydroxy-alpha-mannopyranosides from glucal donors.

[figure: see text] Direct synthetic access to 2-hydroxy-alpha-mannopyranosides from glucal donors is accomplished via a one-pot stereoselective oxidative glycosylation reaction, employing the reagent combination of dibenzothiophene bis(triflate) and dibenzothiophene-5-oxide.[1]

References

  1. Stereoselective synthesis of 2-hydroxy-alpha-mannopyranosides from glucal donors. Kim, J.Y., Di Bussolo, V., Gin, D.Y. Org. Lett. (2001) [Pubmed]
 
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