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Zhang, H. et al.

Highly efficient chiral metal cluster systems derived from Ru3(CO)12 and chiral diiminodiphosphines for the asymmetric transfer hydrogenation of ketones.

The chiral Ru cluster-based catalyst systems generated in situ from Ru3(CO)12 and chiral diiminodiphosphine tetradentate ligands effected asymmetric transfer hydrogenation of propiophenone in 2-propanol, leading to 1-phenyl-1-propanol in 94% yield and with 96% ee.[1]

References

Highly efficient chiral metal cluster systems derived from Ru3(CO)12 and chiral diiminodiphosphines for the asymmetric transfer hydrogenation of ketones. Zhang, H., Yang, C.B., Li, Y.Y., Donga, Z.R., Gao, J.X., Nakamura, H., Murata, K., Ikariya, T. Chem. Commun. (Camb.) (2003) [Pubmed]

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