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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Termination of Mn(III)-based oxidative cyclizations by trapping with azide.

The radicals formed in Mn(III)-based oxidative free-radical cyclizations of beta-keto esters and malonate esters can be trapped with sodium azide and Mn(III) to give cyclic and bicyclic azides in 30-80% yield. Reduction of the azide gives bi- and tricyclic lactams. [reaction: see text][1]

References

  1. Termination of Mn(III)-based oxidative cyclizations by trapping with azide. Snider, B.B., Duvall, J.R. Org. Lett. (2004) [Pubmed]
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