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 Li,  Yang,  
 

A novel synthesis of functionalized allylsilanes.

A novel facile synthesis of substituted and functionalized allylsilane has been developed. This essentially one-pot procedure involves (1) (dimethylphenylsilyl)methyl cerium chloride addition to cyclopropyl ketone and (2) MgI(2) etherate-mediated Julia homoallylic transposition of the corresponding cyclopropyl carbinol. The bifunctional homoiodo allylsilanes, readily accessible by this method, would be useful and versatile synthons in organic synthesis. [reaction: see text][1]

References

  1. A novel synthesis of functionalized allylsilanes. Li, W.D., Yang, J.H. Org. Lett. (2004) [Pubmed]
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