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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Short asymmetric synthesis of (-)- and (+)-cis-lauthisan.

The asymmetric synthesis of both enantiomers of cis-lauthisan (3) is achieved in only six steps from diethyl pimelate (4), the key steps being the diastereodivergent reduction of beta-ketosulfoxide 7 and the highly cis-stereoselective Et(3)SiH/TMSOTf-promoted reductive cyclization of enantiopure hydroxy sulfinyl ketones (S)-14 and (R)-14.[1]

References

  1. Short asymmetric synthesis of (-)- and (+)-cis-lauthisan. Carreño, M.C., Des Mazery, R., Urbano, A., Colobert, F., Solladié, G. Org. Lett. (2005) [Pubmed]
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