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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 
 
 
 
 

Air-stable titanium alkoxide based metal-organic framework as an initiator for ring-opening polymerization of cyclic esters.

An air-stable titanium-organic framework, prepared from Ti(O(i)Pr)(4) and 1,4-butanediol, has been characterized via single-crystal X-ray diffraction, revealing a unique supramolecular structure. Its functionality as a highly active initiator for the ring-opening polymerization of cyclic esters is demonstrated. A discrete titanium trimer containing the related ligand (2R,3R)-2,3-butanediol has also been prepared, and it shows analogous activity as a polymerization initiator.[1]

References

  1. Air-stable titanium alkoxide based metal-organic framework as an initiator for ring-opening polymerization of cyclic esters. Chuck, C.J., Davidson, M.G., Jones, M.D., Kociok-Köhn, G., Lunn, M.D., Wu, S. Inorganic chemistry. (2006) [Pubmed]
 
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