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One-dimensional hierarchical layered KxMnO2 (x < 0.3) nanoarchitectures: synthesis, characterization, and their magnetic properties.

One-dimensional (1D) hierarchical nanostructures of ultralong layered K(x)MnO(2) (x < 0.3) bundles with diameters 50-100 nm and lengths up to 50-100 microm have been successfully prepared by a PEG-assisted hydrothermal method based on the reaction of KMnO(4) with 2-ethylhexanol. The obtained samples ascribe to the monoclinic phase and exhibit ferromagnetic behaviors below 32 K and paramagnetic behaviors above 32 K, which may make this system a promising base material for magnetic devices. A series of contrastive experiments have illustrated that 2-ethylhexanol, PEG 400, KOH, and reaction time play an important role in the synthesis of the nanobundles. A possible growth mechanism has been proposed.[1]

References

  1. One-dimensional hierarchical layered KxMnO2 (x &lt; 0.3) nanoarchitectures: synthesis, characterization, and their magnetic properties. Ge, J., Zhuo, L., Yang, F., Tang, B., Wu, L., Tung, C. The journal of physical chemistry. B, Condensed matter, materials, surfaces, interfaces & biophysical. (2006) [Pubmed]
 
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