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Recovery of nitrogen and phosphorous as struvite from swine waste biogas digester effluent.

OBJECTIVE: To investigate the feasibility of nitrogen and phosphorus recovery from swine waste biogas digester effluent and the effects of pH and NH4+: Mg2+: PO4(3-) molar ratio on its precipitation. METHODS: Precipitation experiments with swine waste biogas digester effluent were conducted at pH 7.5, 8.0, 8.5, and 9.0 together with NH4+: Mg2+: PO4(3-) molar ratios 1: 0.2: 0.08, 1: 1: 1, and 1: 1.5: 1. 5. Chemical and X-ray diffraction (XRD) analysis were done to determine the composition of the precipitate. RESULTS: The highest removal and recovery of NH4+ and PO4(3-) were achieved at pH 9.0 in each experiment. The elevation of pH to 9.0 alone could decrease the initial PO4(3-) concentration from 42 mg L(-1) to 4.7 mg L(-1) and 89.2% PO4(3-) recovery was achieved. The pH-molar ratio combination 9.0-1: 1.5: 1.5 effected 76.5% NH4+ and 68.5% PO4(3-) recovery. The molar ratio of 1: 1: 1 together with pH elevation to 9.0 was determined to be the optimum combination for both NH4+ and PO4(3-) removal as it recovered over 70% and 97% of the initial NH4+ and PO4(3-), respectively. CONCLUSIONS: Nitrogen and phosphorus can be recovered from biogas digester effluent as struvite.[1]

References

  1. Recovery of nitrogen and phosphorous as struvite from swine waste biogas digester effluent. Perera, P.W., Han, Z.Y., Chen, Y.X., Wu, W.X. Biomed. Environ. Sci. (2007) [Pubmed]
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