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Chemical Compound Review:

PubChem2564 2,6-dichloropyridine

Synonyms: ACMC-1CBWR, CCRIS 1727, D73707_ALDRICH, AG-E-70841, AG-L-22649, ...

Yamaguchi, M. et al., Lida, T. et al., Wang, C. et al.

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High impact information on NSC 76606

Photoassisted oxygenation of alkane catalyzed by ruthenium complexes using 2,6-dichloropyridine N-oxide under visible light irradiation [1].
The chloro(Me(2)SO)ruthenium(II) complexes with tris(2-pyridylmethyl)amine or its derivative catalyses the selective, stereospecific, and photoregulative alkane oxidation in the presence of 2,6-dichloropyridine N-oxide under visible light irradiation [1].
The fastest rates of adamantane hydroxylation with 2,6-dichloropyridine N-oxide were achieved by the reductive activation of Ru(IV)(TPFPP)Cl(2) with a zinc amalgam [2].
Biomimetic oxidation of unactivated carbons for structurally different steroids was studied with a model of cytochrome P-450, oxorutheniumporphyrinate complex, which is generated in situ by 2,6-dichloropyridine N-oxide as an oxygen donor and (5,10,15,20-tetramesitylporphyrinate) ruthenium(II) carbonyl complex and HBr as catalysts [3].

References

Photoassisted oxygenation of alkane catalyzed by ruthenium complexes using 2,6-dichloropyridine N-oxide under visible light irradiation. Yamaguchi, M., Kumano, T., Masui, D., Yamagishi, T. Chem. Commun. (Camb.) (2004) [Pubmed]
Fast catalytic hydroxylation of hydrocarbons with ruthenium porphyrins. Wang, C., Shalyaev, K.V., Bonchio, M., Carofiglio, T., Groves, J.T. Inorganic chemistry. (2006) [Pubmed]
Biomimetic oxidation of unactivated carbons in steroids by a model of cytochrome P-450, oxorutheniumporphyrinate complex. Lida, T., Ogawa, S., Miyata, S., Goto, T., Mano, N., Goto, J., Nambara, T. Lipids (2004) [Pubmed]

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