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Chemical Compound Review

Maap-borov     [(1R)-1-[[(2S)-1-[(2S)-2-[2- (3...

Synonyms: AC1NUOXX, 94242-73-6, Meosuc-ala-ala-pro-boroval
 
 
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High impact information on Maap-borov

  • To address questions regarding the mechanism of serine protease catalysis, we have solved two X-ray crystal structures of alpha-lytic protease (alphaLP) that mimic aspects of the transition states: alphaLP at pH 5 (0.82 A resolution) and alphaLP bound to the peptidyl boronic acid inhibitor, MeOSuc-Ala-Ala-Pro-boroVal (0.90 A resolution) [1].
  • In the complex of the MeOSuc-Ala-Ala-Pro-boroVal inhibitor with the enzyme the quadrupole resonance signal was observed at 600-650 kHz, which indicates tetrahedral boron coordination in the active site [2].

References

 
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