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Chemical Compound Review

Cyclobutene     cyclobutene

Synonyms: AG-H-29452, CHEBI:51206, CTK3F0910, AKOS006332479, AC1L2D2W, ...
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High impact information on cyclobutene

  • The epoxidation barriers are only slightly higher for the strained alkenes cyclopropene (DeltaE++ = 14.5 kcal/mol) and cyclobutene (DeltaE++ = 13.7 kcal/mol) than for cyclopentene (DeltaE++ = 12.1 kcal/mol), reflecting the fact there is little relief of strain in the transition state [1].
  • While the irradiation of 9 led principally via SO(2)-N bond homolysis and [1,5] sigmatropic rearrangement to generate 37, 10 proceeded via disrotatory cyclization to the exo cyclobutene 39, and 11 resisted photoisomerization [2].
  • The structure of the cyclobutene was elucidated by IR, MS, (1)H, (13)C, and (77)Se NMR, COSY, HMQC, and HMBC data and X-ray analysis [3].

Associations of cyclobutene with other chemical compounds


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