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Chemical Compound Review:

aminals methanediamine

Synonyms: Diaminomethane, Methanediamine, AG-E-69615, CHEBI:35411, CHEBI:35412, ...

Yoshioka, T. et al., Roller, P.P. et al.

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High impact information on methanediamine

The putrescine analogues diaminomethane, diaminoethane, diaminopropane, and cadaverine also increased the scopolamine content of the DUBOISIA root culture from 0.56% to the respective values of 0.86%, 0.90%, 1.06%, and 1.04% [1].
Mechanistic studies indicate that the intermediates in the nitrosation mixture include the formaldiminium ion, the amine hydrochloride and the diaminomethane (aminal) [2].

References

Effects of Exogenous Polyamines on Tropane Alkaloid Production by a Root Culture of Duboisia myoporoides. Yoshioka, T., Yamagata, H., Ithoh, A., Deno, H., Fujita, Y., Yamada, Y. Planta Med. (1989) [Pubmed]
Inhibitory agents and chemical and mechanisms in the dihalomethane-mediated nitrosation of amines with solid nitrite. Roller, P.P., Keefer, L.K., Slavin, B.W. IARC Sci. Publ. (1980) [Pubmed]

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