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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Spectroscopic studies of the molecular interactions in n-ethylamines and 2-nitropropane/n-ethylamine mixtures.

New experimental results are reported on molecular interactions in the n-ethylamines and 2-nitropropane (2-NP)/n-ethylamine mixtures studied by Raman spectroscopy under pressure in a diamond anvil cell (0-50 GPa) and, at ambient pressure, by infrared spectroscopy. Modifications of the infrared spectra in 2-NP in presence of triethylamine (TEA) or diethylamine (DEA) have been observed at ambient pressure and interpreted as a specific molecular interaction. High-pressure fluorescence in the vicinity of the liquid-solid phase transition of the 2-NP/DEA and 2-NP/monoethylamine mixtures, is highlighted and discussed.[1]

References

  1. Spectroscopic studies of the molecular interactions in n-ethylamines and 2-nitropropane/n-ethylamine mixtures. Gobin, C., Marteau, P., Petitet, J.P. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. (2004) [Pubmed]
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