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Chemical Compound Review:

indium(3+) indium(+3) cation

Synonyms: AG-E-64365, CHEBI:49664, AC1Q1TPE, CTK4E9675, AR-1J2348, ...

Harris, W.R. et al., Prata, M.I. et al., Kim, S.K. et al., Chavatte, K. et al.

Harris, Wang, Brook, Yang, Islam, Chavatte, Mertens, Terriere, Van Den Winkel,

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High impact information on indium(3+)

Compound 1 forms 2:1 (metal:ligand), as well as 1:1 complexes, with In(3+), with fluorescence varying uniquely with the complex stoichiometry [1].
In contrast, the nonamphoteric In(3+) ion binds very slowly in the absence of citrate, presumably due to the rapid formation of polymeric In-hydroxo complexes upon addition of the unchelated metal ion to the pH 7.4 protein solution [2].
The La(3+) and In(3+) chelates of L(1) and L(2) show some structural and dynamic differences in aqueous solution, as studied by (1)H NMR spectroscopy [3].
The complexing capacity of DTPA for radioactive In(3+) strongly depends upon the pH [4].

References

Indium(III)-induced fluorescent excimer formation and extinction in calix[4]arene-fluoroionophores. Kim, S.K., Kim, S.H., Kim, H.J., Lee, S.H., Lee, S.W., Ko, J., Bartsch, R.A., Kim, J.S. Inorganic chemistry. (2005) [Pubmed]
Kinetics of metal ion exchange between citric acid and serum transferrin. Harris, W.R., Wang, Z., Brook, C., Yang, B., Islam, A. Inorganic chemistry. (2003) [Pubmed]
(153)Sm(3+) and (111)In(3+) DTPA derivatives with high hepatic specificity: in vivo and in vitro studies. Prata, M.I., Santos, A.C., Neves, M., Geraldes, C.F., de Lima, J.J. J. Inorg. Biochem. (2002) [Pubmed]
Parameters ruling optimization of radiolabelling of polyamino polycarboxylated functionalized peptide derivatives: a case study report. Chavatte, K., Mertens, J., Terriere, D., Van Den Winkel, P. Nucl. Med. Biol. (2001) [Pubmed]

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