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Chemical Compound Review:

AG-L-18215 tripotassium iridium(+3) cation hexachloride

Synonyms: AC1L4MCN, CTK4C2127, AR-1J2441, AR-1J2442, EINECS 237-854-0, ...

Ji, X. et al.

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High impact information on Tripotassium hexachloroiridate

It is demonstrated via voltammetric and X-ray photoelectron spectroscopy (XPS) analysis that oxygenated species formed at edge plane sites/defects decrease the electron transfer kinetics of ferrocyanide but that the rates for potassium hexachloroiridate(III), hexaammineruthenium(III) chloride and TMPD are insensitive to the oxygenated species [1].
The electron transfer kinetics of ferrocyanide, potassium hexachloroiridate(III), hexaammineruthenium(III) chloride, and N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD) have been examined at basal plane and edge plane pyrolytic graphite electrodes which have been allowed to oxidise in air for various periods of time [1].

References

Oxygenated edge plane sites slow the electron transfer of the ferro-/ferricyanide redox couple at graphite electrodes. Ji, X., Banks, C.E., Crossley, A., Compton, R.G. Chemphyschem : a European journal of chemical physics and physical chemistry. (2006) [Pubmed]

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