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Chemical Compound Review:

Fluoryl trifluoromethane

Synonyms: Fluorym, Fluoroform, Genetron-23, Refrigerant 23, Halocarbon 23, ...

Harmer, M.A. et al., Brunetti, A. et al., Zhao, J. et al., Rutkowski, K.S. et al., Mori, T. et al.

Harmer, Hutchenson,

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Disease relevance of fluoroform

We evaluated a 19F magnetic resonance spectroscopic technique that detects Freon-23 washout as a means of measuring cerebral blood flow in halothane-anesthetized adult cats during and after transient cerebral ischemia produced by vascular occlusion [1].

High impact information on fluoroform

High catalytic activity is demonstrated for the formation of linear alkylbenzenes using a perfluorosulfonic acid catalyst in supercritical fluid reaction media: enhanced alkylation activity is observed in fluoroform (CHF3) compared to carbon dioxide [2].
Reversible activity changes of lipid-coated lipase for enantioselective esterification in supercritical fluoroform [3].
FTIR spectra of mixtures of fluoroform (F3CH) and ammonia (NH3), have been studied in liquid xenon between 5400 and 500 cm-1 [4].

Analytical, diagnostic and therapeutic context of fluoroform

In an effort to expand the range of applications of enhanced-fluidity liquid chromatography (EFLC) to strongly polar and basic analytes, fluoroform (CHF3) was investigated as a fluidity-enhancing agent [5].

References

Cerebral blood flow in experimental ischemia assessed by 19F magnetic resonance spectroscopy in cats. Brunetti, A., Nagashima, G., Bizzi, A., DesPres, D.J., Alger, J.R. Stroke (1990) [Pubmed]
Super acid catalysis in supercritical fluid reaction media for the formation of linear alkyl benzenes. Harmer, M.A., Hutchenson, K.W. Chem. Commun. (Camb.) (2002) [Pubmed]
Reversible activity changes of lipid-coated lipase for enantioselective esterification in supercritical fluoroform. Mori, T., Funasaki, M., Kobayashi, A., Okhata, Y. Chem. Commun. (Camb.) (2001) [Pubmed]
Infrared spectra and relative stability of the F3CH/NH3 H-bonded complex in liquefied Xe. Rutkowski, K.S., Herrebout, W.A., Melikova, S.M., Rodziewicz, P., van der Veken, B.J., Koll, A. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. (2005) [Pubmed]
Reversed-phase separation of basic tricyclic antidepressants using buffered and fluoroform-enhanced fluidity liquid mobile phases. Zhao, J., Olesik, S.V. Journal of chromatography. A. (2001) [Pubmed]

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