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Chemical Compound Review

Hydrazinium     aminoazanium

Synonyms: CHEBI:35324, AC1Q4UCG, CTK0I2020, AR-1J2047, H2NNH3(+), ...
 
 
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High impact information on aminoazanium

  • The permeability sequence was Na+ approximately Li+ approximately hydroxylammonium greater than hydrazinium greater than ammonium greater than guanidinium greater than K+ greater than aminoguanidinium in the ratios 1:0.96:0.94:0.31:0.11:0.093:0.048:0.031 [1].
  • Kinetics and mechanisms of the oxidation of hydrazinium ion (N2H5+) by aqueous Br2, Cl2, and BrCl. Electrophilicity scale for halogens and interhalogens [2].
  • An unusual impurity, the desosamine hydrazinium salt, is generated in this step of the synthetic pathway, and has been isolated and characterized by using one and two-dimensional NMR spectroscopy in conjunction with MS and EDS [3].
  • The kinetics of N2H5+ decomposition and initial HN3 formation increase in a linear manner with the HNO3 concentration (from 1 to 6 M) and with the ultrasonic intensity (from 0.5 to 3.1 W cm-2) [4].
  • The power of chosen carbamates and hydrazinium derivatives (carbazates) to inhibit the hydrolysis of acetylthiocholine by butyrylcholinesterase or acetylcholinesterase was tested [5].
 

Biological context of aminoazanium

  • Removal of some commonly used protecting groups in peptide synthesis by catalytic transfer hydrogenation employing hydrazinium monoformate and 10%Pd on carbon is described [6].
 

Associations of aminoazanium with other chemical compounds

References

  1. Ionic selectivity of the sodium channel of frog skeletal muscle. Campbell, D.T. J. Gen. Physiol. (1976) [Pubmed]
  2. Kinetics and mechanisms of the oxidation of hydrazinium ion (N2H5+) by aqueous Br2, Cl2, and BrCl. Electrophilicity scale for halogens and interhalogens. Jia, Z., Salaita, M.G., Margerum, D.W. Inorganic chemistry. (2000) [Pubmed]
  3. Isolation and identification of a novel impurity of erythromycin A 9-oxime desosaminehydrazinium salt. Zhou, C.C., Huang, X., Ford, K.L., Hollis, L.S. J. Antibiot. (2005) [Pubmed]
  4. Kinetics of hydrazinium nitrate decomposition in nitric acid solutions under the effect of power ultrasound. Venault, L., Moisy, P., Blanc, P., Madic, C. Ultrasonics sonochemistry. (2001) [Pubmed]
  5. Half-inhibition concentrations of new cholinesterase inhibitors. Zdrazilová, P., Stepánková, S., Komers, K., Ventura, K., Cegan, A. Z. Naturforsch., C, J. Biosci. (2004) [Pubmed]
  6. New hydrogen donor: a facile method for the removal of hydrogenolysable protecting groups in Peptide synthesis. Gowda, D.C., Mahesh, B. Protein Pept. Lett. (2002) [Pubmed]
  7. Thermal Decomposition Kinetics of Hydrazinium Cerium 2,3-Pyrazinedicarboxylate Hydrate: A New Precursor for CeO(2). Premkumar, T., Govindarajan, S., Coles, A.E., Wight, C.A. The journal of physical chemistry. B, Condensed matter, materials, surfaces, interfaces & biophysical. (2005) [Pubmed]
 
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