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Chemical Compound Review:

Proton-sponge N,N,N',N'- tetramethylnaphthalene-1,8- diamine

Synonyms: PubChem10327, SureCN28279, AGN-PC-00F40W, AG-E-52091, Proton sponge, ...

Balkowski, G. et al., Bould, J. et al., Fox, M.A. et al.

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High impact information on AI3-62472

Femtosecond fluorescence upconversion and transient absorption experiments have been performed to monitor the photoinduced electronic, geometry, and solvent relaxation dynamics of 1,8-bis(dimethylamino)naphthalene dissolved in methylcyclohexane or n-hexane, n-dodecane, dichloromethane, and acetonitrile [1].
The molecular structure of (PSH+)(nido-7,8-C2B9H12-) determined by neutron diffraction (PS = proton sponge, 1,8-bis(dimethylamino)naphthalene) [2].
Platination has occurred on the {B10} subcluster of 1, interesting in that B16H20 itself deprotonates on the {B8} subcluster: the reference 16-vertex [B16H19]- anion 1a, prepared by deprotonation of 1 with 1,8-bis(dimethylamino)naphthalene, is also structurally characterised [3].

References

Femtosecond excited state studies of the two-center three-electron bond driven twisted internal charge transfer dynamics in 1,8-bis(dimethylamino)naphthalene. Balkowski, G., Szemik-Hojniak, A., van Stokkum, I.H., Zhang, H., Buma, W.J. The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory. (2005) [Pubmed]
The molecular structure of (PSH+)(nido-7,8-C2B9H12-) determined by neutron diffraction (PS = proton sponge, 1,8-bis(dimethylamino)naphthalene). Fox, M.A., Goeta, A.E., Howard, J.A., Hughes, A.K., Johnson, A.L., Keen, D.A., Wade, K., Wilson, C.C. Inorganic chemistry. (2001) [Pubmed]
Macropolyhedral boron-containing cluster chemistry. The reaction of B16H20 and B14H18 with [PtMe2(PMe2Ph)2] to give [(PMe2Ph)2PtB16H17Me] and [(PMe2Ph)2PtB14H16]. Bould, J., Jelínek, T., Barrett, S.A., Coles, S.J., Hursthouse, M.B., Thornton-Pett, M., Stíbr, B., Kennedy, J.D. Dalton transactions (Cambridge, England : 2003) (2005) [Pubmed]

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