High impact information on methylcyclohexane

• The high power decoupling (13)C NMR and Raman spectroscopies were used to identify structure transitions of the mixed CH(4) + C(2)H(6) hydrates (sII) and hydrocarbons (methylcyclohexane, isopentane) + CH(4) hydrates (sH) [1].
• The metal-loaded beads were analyzed by laser-activated membrane introduction mass spectroscopy (LAMIMS) for catalytic activity using methylcyclohexane dehydrogenation to toluene as a probe reaction [2].
• This study investigated the effects of C7 and C9 aliphatic (n-heptane, n-nonane), naphthenic (methylcyclohexane, 1,2,4-trimethylcyclohexane (TMCH)) and aromatic (toluene, 1,2,4-trimethylbenzene (TMB)) hydrocarbons on the production of reactive oxygen species (ROS) and reactive nitrogen species (RNS) in rat brain synaptosome fraction [3].
• 1cp, 1ep, and 1ee formed gels with cyclohexane, methylcyclohexane, and several alcoholic solvents, but scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observations revealed that their superstructures constructed in the organogels are very different [4].
• Femtosecond fluorescence upconversion and transient absorption experiments have been performed to monitor the photoinduced electronic, geometry, and solvent relaxation dynamics of 1,8-bis(dimethylamino)naphthalene dissolved in methylcyclohexane or n-hexane, n-dodecane, dichloromethane, and acetonitrile [5].

Biological context of methylcyclohexane

• This study investigates the effects of aliphatic (n-heptane, n-nonane), naphtenic (methylcyclohexane, 1,2,4-trimethylcyclohexane (TMCH)), and aromatic (methylbenzene, 1,2,4-trimethylbenzene (TMB)) hydrocarbons on respiratory burst in human granulocytes [6].
• A reconstituted hydroxylation system consisting of electrophoretically homogeneous phenobarbital-inducible rabbit liver microsomal cytochrome P-450 (P-450 LM2), NADPH-cytochrome P-450 reductase, phospholipid, buffer, NADPH, and O2 was used to oxidize four cyclohexane derivatives: cyclohexene, methylcyclohexane, norcarane and norbornane [7].

Associations of methylcyclohexane with other chemical compounds

• Fluorescence spectrum of the benzyl radical in methylcyclohexane at 4.2 K [8].
• Two-phase coexistence curves were measured for ternary solutions of bimodal polystyrene in methylcyclohexane with the molecular weight ratio near the tricritical value 23 [9].

Analytical, diagnostic and therapeutic context of methylcyclohexane

• All of them form supramolecular stacks in apolar methylcyclohexane (MCH) solution as demonstrated by concentration- and temperature-dependent absorption, circular dichroism, and fluorescence studies [10].

References