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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Mono- and dinuclear tricarbonyltechnetium(I) complexes with thiosemicarbazones.

[NEt4]2[Tc(CO)3Cl3] reacts with thiosemicarbazones derived from 2,2'-dipyridyl ketone ( HL3) and 4-acetylpyridine (HL4) to form stable technetium(I) complexes of the compositions [Tc(CO)3Cl(HL3-Npy,Npy)] and [Tc2(CO)6Cl2(micro-HL4-Npy,S)]. Whereas exclusively the pyridine nitrogen atoms are involved in coordination in the monomeric complex, the binuclear compound represents the first technetium complex with a coordinated thiosemicarbazone functionality.[1]

References

  1. Mono- and dinuclear tricarbonyltechnetium(I) complexes with thiosemicarbazones. Pereiras-Gabián, G., Vázquez-López, E.M., Braband, H., Abram, U. Inorganic chemistry. (2005) [Pubmed]
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