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Chemical Compound Review:

CHEBI:30251 carbon monoxide; iron

Synonyms: NSC-158658, NSC158658, [Fe(CO)5]

Mahajan, D. et al., Gedanken, A., Janzen, C. et al., Portius, P. et al., Farrugia, L.J. et al.

Farrugia, Evans, Gedanken, Mahajan, Papish, Pandya,

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High impact information on IRON PENTACARBONYL

Unraveling the photochemistry of Fe(CO)5 in solution: observation of Fe(CO)3 and the conversion between 3Fe(CO)4 and 1Fe(CO)4(Solvent) [1].
Experimental X-ray charge density studies on the binary carbonyls Cr(CO)6, Fe(CO)5, and Ni(CO)4 [2].
The decomposition kinetics of Fe(CO)5 and Mo(CO)6 induced by sonolysis in hexadecane solvent was studied as a function of temperature (303-343 K) under an inert atmosphere [3].
Suslick, in his original work, sonicated Fe(CO)5 either as a neat liquid or in a decalin solution and obtained 10-20 nm size amorphous iron nanoparticles [4].
The reaction of iron pentacarbonyl [Fe(CO)5] with the plasma gases Ar/O2 to form nanosized particles was followed by in situ particle mass spectrometry [5].

References

Unraveling the photochemistry of Fe(CO)5 in solution: observation of Fe(CO)3 and the conversion between 3Fe(CO)4 and 1Fe(CO)4(Solvent). Portius, P., Yang, J., Sun, X.Z., Grills, D.C., Matousek, P., Parker, A.W., Towrie, M., George, M.W. J. Am. Chem. Soc. (2004) [Pubmed]
Experimental X-ray charge density studies on the binary carbonyls Cr(CO)6, Fe(CO)5, and Ni(CO)4. Farrugia, L.J., Evans, C. The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory. (2005) [Pubmed]
Sonolysis induced decomposition of metal carbonyls: kinetics and product characterization. Mahajan, D., Papish, E.T., Pandya, K. Ultrasonics sonochemistry. (2004) [Pubmed]
Using sonochemistry for the fabrication of nanomaterials. Gedanken, A. Ultrasonics sonochemistry. (2004) [Pubmed]
Formation and in situ sizing of gamma-Fe2O3 nanoparticles in a microwave flow reactor. Janzen, C., Wiggers, H., Knipping, J., Roth, P. Journal of nanoscience and nanotechnology. (2001) [Pubmed]

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