Disease relevance of IRON PENTACARBONYL

• Iron overload was obtained with a diet supplemented by 3% iron carbonyl during a 6-week period [1].
• Extracts of tumor ascites depleted of mononuclear phagocytes by iron carbonyl treatment showed little suppressor activity [2].
• In this limited first case series of iron carbonyl ingestion, serious toxicity did not occur [3].

High impact information on IRON PENTACARBONYL

• In contrast, Hfe (-/-) mice had considerable parenchymal iron deposition as well, in a pattern similar to that observed in wild-type mice treated with iron carbonyl [4].
• A convenient one-pot procedure to afford bicyclic molecules by stereospecific iron carbonyl mediated [6 + 2] ene-type cyclization: a possible approach to gelsemine [5].
• High-temperature (300 degrees C) aging of iron-oleic acid metal complex, which was prepared by the thermal decomposition of iron pentacarbonyl in the presence of oleic acid at 100 degrees C, was found to generate monodisperse iron nanoparticles [6].
• Biomimetic hydrogen evolution catalyzed by an iron carbonyl thiolate [7].
• BACKGROUND: Skin injury leads to the release of heme, a potent prooxidant which is degraded by heme oxygenase-1 (HO-1) to carbon monoxide, iron, and biliverdin, subsequently reduced to bilirubin [8].

Biological context of IRON PENTACARBONYL

• Concurrent sonolysis of iron pentacarbonyl and poly(ethylene glycol)-400 (PEG-400) in hexadecane solvent proceeds via zero-order kinetics and results in Fe nanoparticles encapsulated in PEG-400 (Fe-PEG) [9].
• Iron carbonyl, a tracer for phagocytosis in scanning electron microscopy [10].

Anatomical context of IRON PENTACARBONYL

• Furthermore, the NK population did not contain pre-activated macrophages since pre-activated cells were removed on glass bead columns or by iron carbonyl and a magnet; treatments which have been previously shown not to affect NK cells [11].
• Spleen cells reactive with spherules could not be depleted by treatment with iron carbonyl, antiimmunoglobulin plus complement, or anti-brain-associated theta plus complement, but they were partially or completely depleted after rosette formation with erythrocytes coated with antibody or murine complement [12].
• Human peripheral blood mononuclear cells and polymorphonuclear (PMN) leukocytes, separated by Ficoll-Hypaque have been incubated with a preparation containing iron carbonyl, and studied by scanning electron microscopy (SEM) in the backscattered electron imaging (BEI) mode [10].
• Iron, in the form of iron carbonyl, has been found to be an excellent marker for the phagocytic activity of granulocytes and monocytes [13].

Associations of IRON PENTACARBONYL with other chemical compounds

• FTIR studies of iron-carbonyl intermediates in allylic alcohol photoisomerization [14].
• The Fourier transform infrared (FTIR) absorption spectra of iron-carbonyl intermediate species such as [Fe(CO)(5)], [Fe(CO)(4)(R-C(3)H(4)OH)], and more importantly the pi-allyl iron-carbonyl hydride species [FeH(CO)(3)(R-C(3)H(3)OH)] (R=H, Me, Ph) were recorded during the catalytic process using [Fe(3)(CO)(12)] as the catalytic precursor [14].
• Visualization of cellular HO-2 expression aids in assessment of potential sites of carbon monoxide, iron, and bilirubin production within the nervous system [15].
• The high-pressure carbon monoxide (HiPco) process for producing single-wall carbon nanotubes (SWNTs) uses iron pentacarbonyl as the source of iron for catalyzing the Boudouard reaction [16].
• Polyvinylpyrrolidone (PVP)-coated iron oxide nanoparticles were prepared by the thermal decomposition of Fe(CO)(5) (iron pentacarbonyl) in one step [17].

Gene context of IRON PENTACARBONYL

• The magnetic microspheres are prepared from BSA and iron pentacarbonyl, or from BSA and iron acetate [18].

Analytical, diagnostic and therapeutic context of IRON PENTACARBONYL

• We adopted the techniques such as Ficoll-Isopaque centrifugation, plastic dish treatment and iron carbonyl treatment for this purpose [19].

References