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Chemical Compound Review:

Triethylfosfat 1-diethoxyphosphoryloxyethane

Synonyms: CPD-3703, NSC-2677, CCRIS 4882, AG-K-71982, ACMC-209pe7, ...

Aschmann, S.M. et al., Böttger, S.A. et al., Salthammer, T. et al., Horne, I. et al., Hong, C.I. et al.

Salthammer, Fuhrmann, Uhde, Böttger, McClintock,

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High impact information on NSC2677

The 5'-nucleotides were prepared by direct phosphorylation of the corresponding ribonucleosides with POCl3 and triethyl phosphate [1].
Rate constants for the reactions of OH radicals and NO(3) radicals with diethyl methylphosphonate [DEMP, (C(2)H(5)O)(2)P(O)CH(3)], diethyl ethylphosphonate [DEEP, (C(2)H(5)O)(2)P(O)C(2)H(5)], and triethyl phosphate [TEP, (C(2)H(5)O)(3)PO] have been measured at 296 +/- 2 K and atmospheric pressure of air using relative rate methods [2].
Molecular modelling of triethyl phosphate in the active site of OpdA confirmed a reduction in the size of the large subsite relative to OPH [3].
Flame retardants in the indoor environment -- Part II: release of VOCs (triethylphosphate and halogenated degradation products) from polyurethane [4].
The embryos of the sea urchin Lytechinus variegatus are capable of surviving chronic exposure to inorganic sodium phosphate and organic triethyl phosphate concentrations as high as 6 and 1000 mg l(-1) seawater, respectively [5].

References

Synthesis and antitumor activity of 5'-phosphates and cyclic 3',5'-phosphates derived from biologically active nucleosides. Hong, C.I., Tritsch, G.L., Mittelman, A., Hebborn, P., Chheda, G.B. J. Med. Chem. (1975) [Pubmed]
Atmospheric chemistry of diethyl methylphosphonate, diethyl ethylphosphonate, and triethyl phosphate. Aschmann, S.M., Tuazon, E.C., Atkinson, R. The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory. (2005) [Pubmed]
Functional effects of amino acid substitutions within the large binding pocket of the phosphotriesterase OpdA from Agrobacterium sp. P230. Horne, I., Qiu, X., Ollis, D.L., Russell, R.J., Oakeshott, J.G. FEMS Microbiol. Lett. (2006) [Pubmed]
Flame retardants in the indoor environment -- Part II: release of VOCs (triethylphosphate and halogenated degradation products) from polyurethane. Salthammer, T., Fuhrmann, F., Uhde, E. Indoor air. (2003) [Pubmed]
The effects of organic and inorganic phosphates on fertilization and early development in the sea urchin Lytechinus variegatus (Echinodermata: Echinoidea). Böttger, S.A., McClintock, J.B. Comp. Biochem. Physiol. C Toxicol. Pharmacol. (2001) [Pubmed]

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