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Chemical Compound Review

Molykote     disulfanylidenemolybdenum

Synonyms: Motimol, Molybdenite, Molysulfide, T-Powder, Nichimoly C, ...
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High impact information on disulfanylidenemolybdenum


Associations of disulfanylidenemolybdenum with other chemical compounds


Gene context of disulfanylidenemolybdenum

  • This angular distortion (theta = 29.5 degrees in (Tp*)MoO(qdt); 21.3 degrees in (Tp*)MoO(bdt)) observed between the MoS2 and S-C=C-S planes may contribute to the electronic structure of these oxo-Mo dithiolene systems by controlling the extent of S p-Mo d orbital overlap [8].
  • (1) With aqueous cyanide MoS2 gave thio-bridged complex anions [(Mo(CN)6)2(mu-S)]6- and [(Mo(CN)4(mu-S))2]6-. Under prebiotic conditions such complexes could have been formed similarly from molybdenite and may have been precursors of molybdoenzymes [9].
  • TGA of the MoS2 nanorods in air and nitrogen atmosphere has also been studied [10].
  • TEM showed onset growth of MoS2 nanorods within the hydrothermal products itself and in thermally treated products it was prominent with the diameter of the nanorods ranging between 10-20 nm [10].

Analytical, diagnostic and therapeutic context of disulfanylidenemolybdenum


  1. Biomimetic hydrogen evolution: MoS2 nanoparticles as catalyst for hydrogen evolution. Hinnemann, B., Moses, P.G., Bonde, J., Jørgensen, K.P., Nielsen, J.H., Horch, S., Chorkendorff, I., Nørskov, J.K. J. Am. Chem. Soc. (2005) [Pubmed]
  2. Unusual magnetic state in lithium-doped MoS2 nanotubes. Mihailovic, D., Jaglicic, Z., Arcon, D., Mrzel, A., Zorko, A., Remskar, M., Kabanov, V.V., Dominko, R., Gaberscek, M., Gómez-García, C.J., Martínez-Agudo, J.M., Coronado, E. Phys. Rev. Lett. (2003) [Pubmed]
  3. Atmospheric pressure chemical vapor deposition: an alternative route to large-scale MoS2 and WS2 inorganic fullerene-like nanostructures and nanoflowers. Li, X.L., Ge, J.P., Li, Y.D. Chemistry (Weinheim an der Bergstrasse, Germany) (2004) [Pubmed]
  4. Chiral symmetry breaking during the self-assembly of monolayers from achiral purine molecules. Sowerby, S.J., Heckl, W.M., Petersen, G.B. J. Mol. Evol. (1996) [Pubmed]
  5. Synthesis of open-ended MoS2 nanotubes and the application as the catalyst of methanation. Chen, J., Li, S.L., Xu, Q., Tanaka, K. Chem. Commun. (Camb.) (2002) [Pubmed]
  6. Surface selective deposition of Mo(IV) on Ni/TiO2 particles in aqueous solutions. Li, G., Li, W., Zhang, M., Zhang, L., Tao, K. Langmuir : the ACS journal of surfaces and colloids. (2006) [Pubmed]
  7. Comparative study on the selective chalcopyrite bioleaching of a molybdenite concentrate with mesophilic and thermophilic bacteria. Romano, P., Blázquez, M.L., Alguacil, F.J., Muñoz, J.A., Ballester, A., González, F. FEMS Microbiol. Lett. (2001) [Pubmed]
  8. Understanding the origin of metal-sulfur vibrations in an oxo-molybdenum dithiolene complex: relevance to sulfite oxidase. Inscore, F.E., Knottenbelt, S.Z., Rubie, N.D., Joshi, H.K., Kirk, M.L., Enemark, J.H. Inorganic chemistry. (2006) [Pubmed]
  9. Reactions of molybdenum-sulphur compounds with cyanide: chemical evolution and deactivation of molybdoenzymes. Mitchell, P.C., Pygall, C.F. J. Inorg. Biochem. (1979) [Pubmed]
  10. A new hydrothermal route for synthesis of molybdenum disulphide nanorods and related nanostructures. Ota, J.R., Srivastava, S.K. Journal of nanoscience and nanotechnology. (2006) [Pubmed]
  11. Moiré patterns in high resolution electron microscopy images of MoS2. Reyes-Gasga, J., Tehuacanero, S., Yacamán, M.J. Microsc. Res. Tech. (1998) [Pubmed]
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