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Chemical Compound Review

OCTADECANTHIOL     octadecane-1-thiol

Synonyms: Mercaptan C18, O1858_ALDRICH, NSC-5545, AG-E-93378, ACMC-209h55, ...
 
 
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High impact information on Stearyl mercaptan

  • Simulations were performed using butane-, dodecane-, and octadecanethiol passivated nanoparticles [1].
  • The strong hydrophobicity of the ODT adlayer, combined with the addition of the surfactant Tween 80 to the buffer solution that is used in forming the antibody-antigen pairs, minimizes the nonspecific adsorption of proteinaceous materials to the grid regions [2].
  • By constructing self-assembled monolayers of octadecyl mercaptan (C18) on the MALDI probe surface, we were able to generate a surface capable of reversibly binding polypeptides via hydrophobic interactions, which in turn, permits the analyte to be easily concentrated and desalted directly on the probe tip [3].
  • X-ray photoelectron spectroscopy (XPS) studies of spin-coated polyethylene-block-poly(ethylene oxide) (PE-b-PEO) copolymers on 16-mercaptohexadecanoic acid (MHDA)-, octadecanethiol (ODT)-, and 1H,1H,2H,2H-perfluorodecanethiol (PFDT)-covered surfaces have been performed [4].
  • The one-phase reduction of RuCl3 with lithium triethylborohydride as a reductant in tetrahydrofuran in the presence of 1-octanethiol, 1-octadecanethiol, 1,1'-binaphthalene-2,2'-dithiol, or oligoethyleneoxythiol gave organic solvent- and water-soluble thiol-stabilized ruthenium nanoparticles [5].
 

Associations of Stearyl mercaptan with other chemical compounds

  • X-ray photoelectron spectroscopy revealed that SAMs of ODT were more stable than those of ODI, which was supported by experiments that probed desorption of these layers in prewarmed hexadecane [6].
  • The ligand-exchange reaction of octadecanethiol-stabilized ruthenium nanoparticles (2.0 nm) with phenothiazine-linked decanethiol afforded redox-active phenothiazine-functionalized ruthenium nanoparticles (1.9 nm) that showed a reversible redox peak at +0.51 V (vs Ag/0.1 M AgNO3) in the cyclic voltammogram [5].
 

Gene context of Stearyl mercaptan

  • The methodology includes a single-step extraction, followed by gas chromatography with flame photometric detector (FDP) using n-octadecyl mercaptan (n-octadecylthiol) as an internal standard [7].
  • Magnetic and electronic properties are investigated for Pd nanoparticles coated with a TTF-derivative (EDT-TTF(SCH(3))(SC(10)H(20)SH)) and octadecanethiol organic mixed monolayer [8].

References

  1. Wetting properties of passivated metal nanocrystals at liquid-vapor interfaces: a computer simulation study. Tay, K.A., Bresme, F. J. Am. Chem. Soc. (2006) [Pubmed]
  2. Microminiaturized immunoassays using atomic force microscopy and compositionally patterned antigen arrays. Jones, V.W., Kenseth, J.R., Porter, M.D., Mosher, C.L., Henderson, E. Anal. Chem. (1998) [Pubmed]
  3. A desalting approach for MALDI-MS using on-probe hydrophobic self-assembled monolayers. Brockman, A.H., Dodd, B.S., Orlando, R. Anal. Chem. (1997) [Pubmed]
  4. Template-directed adsorption of block copolymers on alkanethiol-patterned gold surfaces. Chandekar, A., Sengupta, S.K., Barry, C.M., Mead, J.L., Whitten, J.E. Langmuir : the ACS journal of surfaces and colloids. (2006) [Pubmed]
  5. New method for facile synthesis of amphiphilic thiol-stabilized ruthenium nanoparticles and their redox-active ruthenium nanocomposite. Tsukatani, T., Fujihara, H. Langmuir : the ACS journal of surfaces and colloids. (2005) [Pubmed]
  6. Comparative study of monolayers self-assembled from alkylisocyanides and alkanethiols on polycrystalline Pt substrates. Geissler, M., Chen, J., Xia, Y. Langmuir : the ACS journal of surfaces and colloids. (2004) [Pubmed]
  7. Analysis of micro-encapsulated d-limonene dimercaptan, a possible herbicide marker for Cannabis sprayed with paraquat, using gas chromatography. Turner, C.E., Ma, C.Y., Russell, M.H., Elsohly, M.A. Bulletin on narcotics. (1981) [Pubmed]
  8. Magnetic and Electronic Properties of Palladium Nanoparticles Coated with pi-Conjugated Tetrathiafulvalenes Derivative. Tu, W., Fukui, K., Miyazaki, A., Enoki, T. The journal of physical chemistry. B, Condensed matter, materials, surfaces, interfaces & biophysical. (2006) [Pubmed]
 
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