High impact information on propane

• High enantioselectivity in rhodium-catalyzed allylic alkylation of 1-substituted 2-propenyl acetates [1].
• Modulatory influence of sodium 2-propenyl thiosulfate from garlic on cyclooxygenase activity in canine platelets: possible mechanism for the anti-aggregatory effect [2].
• These scaffolds were then functionalized and cleaved via four distinct methods, namely traceless reduction, radical cyclization, radical rearrangement, and oxidative elimination, to afford 2-methyl indolines, polycyclic indolines, 2-methyl indoles, and 2-propenyl indolines, respectively [3].
• Ultraviolet photochemistry of trichlorovinylsilane and allyltrichlorosilane: vinyl radical (HCCH2) and allyl radical (H2CCHCH2) production in 193 nm photolysis [4].
• The vinyl radical and the allyl radical are formed promptly from the 193 nm photolysis of their respective trichlorosilane precursors [4].

Biological context of propane

• Sinigrin (2-propenyl glucosinolate) was found to be relatively innocuous to all of the organisms tested but its hydrolysis to yield isothiocyanates, thiocyanates and nitriles resulted in inhibition of growth [5].

Anatomical context of propane

• Isolation and identification of sodium 2-propenyl thiosulfate from boiled garlic (Allium sativum) that oxidizes canine erythrocytes [6].

Associations of propane with other chemical compounds

• By comparison of the transient visible absorption and the 1315 nm I atom absorption from 266 nm photolysis of vinyl iodide and allyl iodide, the absorption cross sections at 404 nm of vinyl radical ((2.9 +/- 0.4) x 10(-19) cm(2)) and allyl radical ((3.6 +/- 0.8) x 10(-19) cm(2)) were derived [4].

Gene context of propane

• For the allyl radical, CC3 adiabatic excitation energies differ from experiment by less than 0.02 eV, while for the (2)Sigma(+) state of CH, significant errors of more than 0.4 eV remain [7].

Analytical, diagnostic and therapeutic context of propane

• Electronic absorption spectra in the 210-250 nm region, were reported for the allyl radical in the vapor phase and subsequent reactions have been investigated by kinetic spectroscopy and gas-liquid chromatography [8].

References