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Chemical Compound Review:

Trioctylamine N,N-dioctyloctan-1-amine

Synonyms: Tricaprylamine, Farmin 08, Alamine 308, Alamine 336, PubChem21346, ...

Wang, L.W. et al., Lin, C.N. et al., Desideri, D. et al., Lu, C.H. et al., Yamamoto, M. et al., et al.

Bhattacharya, Chattopadhyay, Laskar, Banerjee,

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High impact information on 1116-76-3

In comparing triethylamine with trioctylamine, there was no obvious effect to regulate the size distribution of the nanoparticles because they could not function as a capping ligand of the nanoparticles due to their weak coordination to silver [1].
A detailed study of the kinetics for hydrolysis and racemization indicates that increasing the trioctylamine concentration can activate and stabilize the lipase as well as enhance the racemization and non-stereoselective hydrolysis of the thioester [2].
A detailed investigation of trioctylamine concentration on the enzyme activation and stability as well as the kinetic behaviors of the thioester in racemization and enzymatic reaction was conducted, in which good agreement between the experimental data and theoretical results was observed [3].
Reactive extraction of lactic acid using alamine 336 in MIBK: equilibria and kinetics [4].
Vertical ionization potential of TOA was determined utilizing CT transition energy [5].

Biological context of 1116-76-3

Plutonium was separated from uranium by extraction chromatography, using tri- n-octylamine (TNOA), with a decontamination factor higher than 10(6); after elution plutonium was determined by ICP-MS ((239)Pu and (240)Pu) and alpha-spectrometry ((239+240)Pu) after electroplating [6].

Associations of 1116-76-3 with other chemical compounds

A Candida rugosa lipase immobilized on polypropylene powder was employed as the biocatalyst for the enantioselective hydrolysis of (R, S)-suprofen 2,2,2-trifluorothioester in cyclohexane, in which trioctylamine was added as the catalyst to perform in situ racemization of the remaining (R)-thioester [7].

Gene context of 1116-76-3

Extraction of organic acids by ion-pair formation with tri-n-octylamine. Part 7. Comparison of methods for extraction of synthetic dyes from yogurt [8].

Analytical, diagnostic and therapeutic context of 1116-76-3

The sorbate content of commercial yogurt samples is determined by reverse phase liquid chromatography following ion-pair extraction with tri-n-octylamine [9].

References

Size-controlled synthesis of monodispersed silver nanoparticles capped by long-chain alkyl carboxylates from silver carboxylate and tertiary amine. Yamamoto, M., Kashiwagi, Y., Nakamoto, M. Langmuir : the ACS journal of surfaces and colloids. (2006) [Pubmed]
Integration of reactive membrane extraction with lipase-hydrolysis dynamic kinetic resolution of naproxen 2,2,2-trifluoroethyl thioester in isooctane. Lu, C.H., Cheng, Y.C., Tsai, S.W. Biotechnol. Bioeng. (2002) [Pubmed]
Dynamic kinetic resolution of suprofen thioester via coupled trioctylamine and lipase catalysis. Lin, C.N., Tsai, S.W. Biotechnol. Bioeng. (2000) [Pubmed]
Reactive extraction of lactic acid using alamine 336 in MIBK: equilibria and kinetics. Wasewar, K.L., Heesink, A.B., Versteeg, G.F., Pangarkar, V.G. J. Biotechnol. (2002) [Pubmed]
Study of electron donor-acceptor complexes of tri-n-octyl amine with [60]- and [70]fullerenes and some other electron acceptors by absorption spectrophotometric method. Bhattacharya, S., Chattopadhyay, S., Laskar, S., Banerjee, M. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. (2006) [Pubmed]
Determination of (236)U and transuranium elements in depleted uranium ammunition by alpha-spectrometry and ICP-MS. Desideri, D., Meli, M.A., Roselli, C., Testa, C., Boulyga, S.F., Becker, J.S. Analytical and bioanalytical chemistry. (2002) [Pubmed]
Process modeling of the lipase-catalyzed dynamic kinetic resolution of (R, S)-suprofen 2,2,2-trifluoroethyl thioester in a hollow-fiber membrane. Wang, L.W., Cheng, Y.C., Tsai, S.W. Bioprocess and biosystems engineering. (2004) [Pubmed]
Extraction of organic acids by ion-pair formation with tri-n-octylamine. Part 7. Comparison of methods for extraction of synthetic dyes from yogurt. Puttemans, M.L., de Voogt, M., Dryon, L., Massart, D. Journal - Association of Official Analytical Chemists. (1985) [Pubmed]
Extraction of organic acids by ion-pair formation with tri-n-octylamine. Part 6. Determination of sorbic acid, benzoic acid, and saccharin in yogurt. Puttemans, M.L., Branders, C., Dryon, L., Massart, D.L. Journal - Association of Official Analytical Chemists. (1985) [Pubmed]

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