High impact information on Chemistry, Organic

• Recent investigations have shown that cycloaddition reactions, widely used in organic chemistry to form ring compounds, can also be applied to link organic molecules to the (001) surfaces of crystalline silicon, germanium, and diamond [1].
• The present Account is restricted to atmospheric organic chemistry, primarily on the large moon of Saturn [2].
• Another conclusion is that data in the Beilstein Handbook of Organic Chemistry that have been claimed to support the hypothesis that the reductive citric acid cycle originated as a self-organized cycle can more plausibly be interpreted in a different way [3].
• The azide group has a diverse and extensive role in organic chemistry, reflected in the power of azide anion as a strong nucleophile, the role of organic azides as excellent substrates for cycloaddition reactions, the uses of azides as precursors of amines and nitrenes, and azide rearrangements known as the Curtius and Schmidt reactions [4].
• Physical organic chemistry of transition metal carbene complexes. 24. Thermodynamic and kinetic acidities of phenyl-substituted (benzylmethoxycarbene)pentacarbonylchromium(0) complexes. Is there a transition-state imbalance [5]?

Biological context of Chemistry, Organic

• It was synthesized by Harrison et al. in 1970 at the Syntex Institute of Organic Chemistry and Biological Sciences. How can we chart the evolution of this or any other drug [6]?
• DAT general and organic chemistry scores were associated with performance on the microbiology and pathology subtest of NBDE Part I [7].

Associations of Chemistry, Organic with chemical compounds

• This system possesses a high degree of chiroptical activity, which allows the differentiation of one of the smallest homologous elements of organic chemistry, that is, the methyl and ethyl groups attached to the asymmetric carbon, and additionally, which senses a remote chiral center at a position beta to the amine binding group [8].
• The cumulative double bond (C[double bond]C[double bond]N), an important intermediate in synthetic organic chemistry, was successfully prepared via the selective attachment of acrylonitrile to Si(111)-7 x 7 [9].
• Is the tert-butyl chloride solvolysis the most misunderstood reaction in organic chemistry? Evidence against nucleophilic solvent participation in the tert-butyl chloride transition state and for increased hydrogen bond donation to the 1-adamantyl chloride solvolysis transition state [10].
• Physical organic chemistry of transition metal carbene complexes. 23. Kinetic and thermodynamic acidities of cationic benzothienyl- and selenylcarbene complexes of rhenium in aqueous acetonitrile [11].
• The use of polymers other than divinylbenzene crosslinked polystyrene as supports in organic chemistry is discussed [12].

Gene context of Chemistry, Organic

• DERA is the only known aldolase that is able to use aldehydes as both aldol donor and acceptor molecules in the aldol reaction and is, therefore, of particular interest as a biocatalyst in synthetic organic chemistry [13].
• Organic chemistry on cold molecular films: kinetic stabilization of SN1 and SN2 intermediates in the reactions of ethanol and 2-methylpropan-2-ol with hydrogen bromide [14].
• Synthesis of the C1-C11 polyene fragment of apoptolidin with a new sulfur dioxide-based organic chemistry [15].
• A new quantum mechanical scheme to calculate electronic correlation energies, spin-component-scaled MP2, was tested as a tool to predict reaction energies and barriers in computational organic chemistry [16].
• 2005-2006 ACS Division of Organic Chemistry Graduate Fellowship Awards [17].

Analytical, diagnostic and therapeutic context of Chemistry, Organic

• CdSe quantum dots with polymerisable ligands have been incorporated into polystyrene beads, via a suspension polymerisation reaction, as a first step towards the optical encoding of solid supports for application in solid phase organic chemistry [18].
• Local anesthesia was in a profound crisis until the development of modern organic chemistry which led to the synthesis of pure cocaine in 1891 [19].

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