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Chemical Compound Review

BUTADIYNE     buta-1,3-diyne

Synonyms: Biethynyl, Biacetylene, Diacetylene, AG-K-60984, CHEBI:37820, ...
 
 
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Disease relevance of BUTADIYNE

 

High impact information on BUTADIYNE

  • "Naked eye" color detection of proteins was achieved by embedding calixarene receptors within vesicles comprising phospholipids and the chromatic polymer polydiacetylene [2].
  • We describe the application of a colorimetric phospholipid/polydiacetylene (PDA) biomimetic membrane assay in elucidating DP-109 membrane interactions and penetration into lipid bilayers [3].
  • Moreover, the direct electrochemical detection by polydiacetylene supramolecular assemblies not only opens a new path for the use of these membranes in the area of biosensor development but also offers new possibilities for diagnostic applications and screening for binding ligands [1].
  • Stable phosphoinositide (PIP(n))-containing liposomes were prepared using polydiacetylene photochemistry [4].
  • Catalytic oxidative dimerization of the terminal acetylene compounds permits the isolation of the corresponding 1,3-butadiyne derivatives 16-18, with the nitro groups at the ends of the conjugation, in excellent yields [5].
 

Biological context of BUTADIYNE

  • Here we present a detailed biophysical study of a recently developed colorimetric biomimetic membrane assembly constructed from physiological lipid molecules and conjugated polydiacetylene [6].
  • METHODS: The new bio-mimetic membrane assembly, consisting of supramolecular aggregates of lipids and conjugated polydiacetylene, undergoes visible and quantifiable blue-red color transitions upon interaction with penetration enhancers [7].
  • Energy transfer was found to be significantly more efficient from dansyl to the red-form PDA [8].
  • Raman microspectroscopic study on polymerization and degradation processes of a diacetylene derivative at surface enhanced Raman scattering active substrates. 2. Confocal Raman microscopic observation of polydiacetylene adsorbed on active sites [9].
 

Associations of BUTADIYNE with other chemical compounds

  • The excited-state dynamics of an oligomer of polydiacetylene, 2,2,17,17-tetramethyloctadeca-5,9,13-trien-3,7,11,15-tetrayne, dissolved in n-hexane have been studied by femtosecond fluorescence upconversion and polarized transient absorption experiments under one- and two-photon excitation conditions [10].
  • Our results indicate that explosive volcanism may have injected into the atmosphere of early Mars approximately 6 x 10(12) g yr(-1) of acetylene, and approximately 2 x 10(12) g yr(-1) of 1,3-butadiyne, both produced by volcanic lightning, approximately 5 x 10(11) g yr(-1) of ethylene produced by volcanic heat, and 10(13) g yr(-1) of methane [11].
 

Analytical, diagnostic and therapeutic context of BUTADIYNE

References

  1. Electrochemical and Raman studies of the biointeraction between Escherichia coli and mannose in polydiacetylene derivative supported on the self-assembled monolayers of octadecanethiol on a gold electrode. Li, Y., Ma, B., Fan, Y., Kong, X., Li, J. Anal. Chem. (2002) [Pubmed]
  2. Color fingerprinting of proteins by calixarenes embedded in lipid/polydiacetylene vesicles. Kolusheva, S., Zadmard, R., Schrader, T., Jelinek, R. J. Am. Chem. Soc. (2006) [Pubmed]
  3. Membrane interactions and metal ion effects on bilayer permeation of the lipophilic ion modulator DP-109. Kolusheva, S., Friedman, J., Angel, I., Jelinek, R. Biochemistry (2005) [Pubmed]
  4. Phosphoinositide-containing polymerized liposomes: stable membrane-mimetic vesicles for protein-lipid binding analysis. Ferguson, C.G., James, R.D., Bigman, C.S., Shepard, D.A., Abdiche, Y., Katsamba, P.S., Myszka, D.G., Prestwich, G.D. Bioconjug. Chem. (2005) [Pubmed]
  5. Carbon networks based on 1,5-naphthalene units. Synthesis of 1,5-naphthalene nanostructures with extended pi-conjugation. Rodríguez, J.G., Tejedor, J.L. J. Org. Chem. (2002) [Pubmed]
  6. Biomimetic lipid/polymer colorimetric membranes: molecular and cooperative properties. Kolusheva, S., Wachtel, E., Jelinek, R. J. Lipid Res. (2003) [Pubmed]
  7. A new colorimetric assay for studying and rapid screening of membrane penetration enhancers. Evrard, D., Touitou, E., Kolusheva, S., Fishov, Y., Jelinek, R. Pharm. Res. (2001) [Pubmed]
  8. Modulating fluorescence resonance energy transfer in conjugated liposomes. Li, X., McCarroll, M., Kohli, P. Langmuir : the ACS journal of surfaces and colloids. (2006) [Pubmed]
  9. Raman microspectroscopic study on polymerization and degradation processes of a diacetylene derivative at surface enhanced Raman scattering active substrates. 2. Confocal Raman microscopic observation of polydiacetylene adsorbed on active sites. Itoh, K., Kudryashov, I., Yamagata, J., Nishizawa, T., Fujii, M., Osaka, N. The journal of physical chemistry. B, Condensed matter, materials, surfaces, interfaces & biophysical. (2005) [Pubmed]
  10. Femtosecond Spectroscopic Studies of the One- and Two-Photon Excited-State Dynamics of 2,2,17,17-Tetramethyloctadeca-5,9,13-trien-3,7,11,15-tetrayne: A Trimeric Oligodiacetylene. Balkowski, G.M., Groeneveld, M., Zhang, H., Hendrikx, C.C., Polhuis, M., Zuilhof, H., Buma, W.J. The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory. (2006) [Pubmed]
  11. Production of low molecular weight hydrocarbons by volcanic eruptions on early Mars. Segura, A., Navarro-González, R. Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life. (2005) [Pubmed]
  12. Electronic structure of a polydiacetylene nanowire fabricated on highly ordered pyrolytic graphite. Akai-Kasaya, M., Shimizu, K., Watanabe, Y., Saito, A., Aono, M., Kuwahara, Y. Phys. Rev. Lett. (2003) [Pubmed]
  13. Chromatic immunoassay based on polydiacetylene vesicles. Su, Y.L., Li, J.R., Jiang, L. Colloids and surfaces. B, Biointerfaces. (2004) [Pubmed]
 
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