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Chemical Compound Review

Triflat     trifluoromethanesulfonate

Synonyms: TfO(-), CHEBI:48547, AC1MBZ4O, CF3SO3(-), Trifluormethansulfonat, ...
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Psychiatry related information on trifluoromethanesulfonic acid

  • In addition, using the promoter system 1-(benzensulfinyl)piperidinetrifluoromethanesulfonic anhydride, the product yield was improved and the reaction time was reduced in comparison with the N-iodosuccinimidetrifluoromethanesulfonic acid- and dimethyl (thiomethyl) sulfonium trifluoromethanesulfonate-promoted systems [1].

High impact information on trifluoromethanesulfonic acid

  • Key steps of this approach to 1 involve a siloxy-epoxide semipinacol rearrangement of 5 to 6, a B-alkyl Suzuki-Miyaura coupling reaction by using enol trifluoromethanesulfonate 19 and a substrate-directed hydrogenation reaction of 24 [2].
  • [reaction: see text] Treatment of sarcophytoxide with trimethylsilyl trifluoromethanesulfonate afforded an aromatic ketone as an unusual cyclization product [3].
  • We have studied interhalogen/silver trifluoromethanesulfonate (IX/AgOTf) promoted glycosylations and found differences in the sensitivity of the formed oxocarbenium ions (e.g. from compounds with or without participating groups) toward halide nucleophiles [4].
  • 1-Heptyl-4-(butyl-4-sulfonic acid) triazolium trifluoromethanesulfonate, 6b, in its role as a Brønsted acid, is an effective solvent/catalyst for high yield esterification and hetero-Michael addition reactions and may be recycled for repetitive use [5].
  • The reaction of AgX, where X = trifluoroacetate (CF(3)CO(2)(-), tfa), nitrate (NO(3)(-)), trifluoromethanesulfonate (triflate, CF(3)SO(3)(-), OTf), hexafluorophosphate (PF(6)(-)), or perchlorate (ClO(4)(-)), with 2,2',3' '-tripyridylamine (tpa) yields five novel silver(I) complexes, which have been structurally characterized [6].

Biological context of trifluoromethanesulfonic acid


Anatomical context of trifluoromethanesulfonic acid


Associations of trifluoromethanesulfonic acid with other chemical compounds


Gene context of trifluoromethanesulfonic acid


Analytical, diagnostic and therapeutic context of trifluoromethanesulfonic acid


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