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Chemical Compound Review

AC1O3R1O     copper; potassium; silicon; tungsten;...

Synonyms: K6[SiCu(OH2)W11O39]nH2O
 
 
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Disease relevance of AIDS088251

 

Psychiatry related information on AIDS088251

  • The multilayer films also exhibit high optical contrast, suitable response time and low operation potential due to the presence of mono-lacunary-substituted polyoxometalate and transition metal complex [6].
 

High impact information on AIDS088251

  • Micelle directed polyoxometalate nanoparticles were synthesized by depositing H(3+)(x)()PV(x)()Mo(12)(-)(x)()O(40) (x = 0, 2) by precipitation on micelles prepared from cesium dodecyl sulfate [7].
  • The high-valent iron-oxo species of polyoxometalate, if it can be made, will be a highly potent catalyst for C-H hydroxylation and double-bond epoxidation [8].
  • 51V magic angle spinning NMR spectroscopy of six-coordinate Lindqvist oxoanions: a sensitive probe for the electronic environment in vanadium-containing polyoxometalates. Counterions dictate the 51V fine structure constants in polyoxometalate solids [9].
  • Electron and oxygen transfer in polyoxometalate, H(5)PV(2)Mo(10)O(40), catalyzed oxidation of aromatic and alkyl aromatic compounds: evidence for aerobic Mars-van Krevelen-type reactions in the liquid homogeneous phase [10].
  • Within the 9-armed POM-cored dendrimer series, the reaction kinetics were susceptible to the nature of the peripheral endgroups [11].
 

Chemical compound and disease context of AIDS088251

  • On the basis of TI50 [median cytotoxic concentration (CC50)/median effective concentration (EC50)], the in vitro anti-HIV-1 activity of PM-104 is favorably comparable to that of a heteropolyoxotungstate PM-19 K7[PTi2W10O40].6H2O, which is one of the most potent HIV-1 inhibitors among the polyoxometalates so far tested [12].
 

Biological context of AIDS088251

 

Anatomical context of AIDS088251

 

Associations of AIDS088251 with other chemical compounds

 

Gene context of AIDS088251

  • Strains of virus with acquired resistance to PM523 had mutations in the amino acids substrates in HA1 head, and amino acid changes occurred in the interface peptide of the trimers of HA [17].
  • We synthesized two surfactant-encapsulated polyoxometalate (POM) clusters (SECs), (DODA)(15)[H(3)Mo(57)V(6)(NO)(6)O(189)(H(2)O)(12)(VO)(6)].13H(2)O (SEC-2, DODA: dimethyldioctadecyl ammonium) and (DODA)(12)[Eu(H(2)O)P(5)W(30)O(110)].28H(2)O (SEC-3) [23].
  • This proposed method was based on the formation of a green charge-transfer polyoxometalate, molybdo-11-tungstophosphate-3,3',5,5'-tetramethylbenzidine-N-propanesulfonic, which was solubilized and stabilized in a PVA medium; the wavelength of the maximum absorption was at 660 nm [24].
 

Analytical, diagnostic and therapeutic context of AIDS088251

References

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  2. Synergistic anti-influenza virus A (H1N1) activities of PM-523 (polyoxometalate) and ribavirin in vitro and in vivo. Shigeta, S., Mori, S., Watanabe, J., Soeda, S., Takahashi, K., Yamase, T. Antimicrob. Agents Chemother. (1997) [Pubmed]
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  6. Electrochromic multilayer films of tunable color by combination of copper or iron complex and monolacunary dawson-type polyoxometalate. Gao, G., Xu, L., Wang, W., An, W., Qiu, Y., Wang, Z., Wang, E. The journal of physical chemistry. B, Condensed matter, materials, surfaces, interfaces & biophysical. (2005) [Pubmed]
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  8. The high-valent iron-oxo species of polyoxometalate, if it can be made, will be a highly potent catalyst for C-H hydroxylation and double-bond epoxidation. Kumar, D., Derat, E., Khenkin, A.M., Neumann, R., Shaik, S. J. Am. Chem. Soc. (2005) [Pubmed]
  9. 51V magic angle spinning NMR spectroscopy of six-coordinate Lindqvist oxoanions: a sensitive probe for the electronic environment in vanadium-containing polyoxometalates. Counterions dictate the 51V fine structure constants in polyoxometalate solids. Huang, W., Todaro, L., Francesconi, L.C., Polenova, T. J. Am. Chem. Soc. (2003) [Pubmed]
  10. Electron and oxygen transfer in polyoxometalate, H(5)PV(2)Mo(10)O(40), catalyzed oxidation of aromatic and alkyl aromatic compounds: evidence for aerobic Mars-van Krevelen-type reactions in the liquid homogeneous phase. Khenkin, A.M., Weiner, L., Wang, Y., Neumann, R. J. Am. Chem. Soc. (2001) [Pubmed]
  11. Synthesis of 9- and 27-armed tetrakis(diperoxotungsto)phosphate-cored dendrimers and their use as recoverable and reusable catalysts in the oxidation of alkenes, sulfides, and alcohols with hydrogen Peroxide. Nlate, S., Plault, L., Astruc, D. Chemistry (Weinheim an der Bergstrasse, Germany) (2006) [Pubmed]
  12. Antiviral activity of polyoxomolybdoeuropate PM-104 against human immunodeficiency virus type 1. Inouye, Y., Tokutake, Y., Yoshida, T., Yamamoto, A., Yamase, T., Nakamura, S. Chem. Pharm. Bull. (1991) [Pubmed]
  13. Polyoxometalate-supported Y- and YbIII-hydroxo/oxo clusters from carbonate-assisted hydrolysis. Fang, X., Anderson, T.M., Benelli, C., Hill, C.L. Chemistry (Weinheim an der Bergstrasse, Germany) (2005) [Pubmed]
  14. Unique guest-inclusion properties of a breathing ionic crystal of K3[Cr3O(OOCH)6(H2O)3][alpha-SiW12O40].16 H2O. Uchida, S., Mizuno, N. Chemistry (Weinheim an der Bergstrasse, Germany) (2003) [Pubmed]
  15. Pharmacokinetics of antiviral polyoxometalates in rats. Ni, L., Boudinot, F.D., Boudinot, S.G., Henson, G.W., Bossard, G.E., Martellucci, S.A., Ash, P.W., Fricker, S.P., Darkes, M.C., Theobald, B.R. Antimicrob. Agents Chemother. (1994) [Pubmed]
  16. Mechanism of polyoxometalate-mediated inactivation of DNA polymerases: an analysis with HIV-1 reverse transcriptase indicates specificity for the DNA-binding cleft. Sarafianos, S.G., Kortz, U., Pope, M.T., Modak, M.J. Biochem. J. (1996) [Pubmed]
  17. Targets of anti-influenza chemotherapy other than neuraminidase and proton pump. Shigeta, S. Antivir. Chem. Chemother. (2001) [Pubmed]
  18. Recent progress in anti-influenza chemotherapy. Shigeta, S. Drugs in R&D. (1999) [Pubmed]
  19. Enantiopure 1,1'-binaphthyl-based polyoxometalate-containing molecular hybrids. Lu, M., Kang, J., Wang, D., Peng, Z. Inorganic chemistry. (2005) [Pubmed]
  20. Polyoxometalate-modified carbon nanotubes: new catalyst support for methanol electro-oxidation. Pan, D., Chen, J., Tao, W., Nie, L., Yao, S. Langmuir : the ACS journal of surfaces and colloids. (2006) [Pubmed]
  21. A dimeric titanium-containing polyoxometalate. Synthesis, characterization, and catalysis of H2O2-based thioether oxidation. Kholdeeva, O.A., Maksimov, G.M., Maksimovskaya, R.I., Kovaleva, L.A., Fedotov, M.A., Grigoriev, V.A., Hill, C.L. Inorganic chemistry. (2000) [Pubmed]
  22. Photocatalytic degradation of aqueous 4-chlorophenol by silica-immobilized polyoxometalates. Yue, B., Zhou, Y., Xu, J., Wu, Z., Zhang, X., Zou, Y., Jin, S. Environ. Sci. Technol. (2002) [Pubmed]
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  24. Novel spectrophotometric method for the determination of molybdenum in a PVA medium. Di, J., Wu, Y., Tu, Y., Bi, S. Analytical sciences : the international journal of the Japan Society for Analytical Chemistry. (2002) [Pubmed]
  25. New heterogeneous polyoxometalate based mesoporous catalysts for hydrogen peroxide mediated oxidation reactions. Vasylyev, M.V., Neumann, R. J. Am. Chem. Soc. (2004) [Pubmed]
  26. Polyoxometalates as pH-sensitive probes in self-assembled multilayers. Liu, S., Kurth, D.G., Volkmer, D. Chem. Commun. (Camb.) (2002) [Pubmed]
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  28. Covalent immobilization of a TiW5 polyoxometalate on derivatized silicon surfaces. Errington, R.J., Petkar, S.S., Horrocks, B.R., Houlton, A., Lie, L.H., Patole, S.N. Angew. Chem. Int. Ed. Engl. (2005) [Pubmed]
 
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